How can I see the people who have not joined yet and whose invitations are pending?

Navigate to People > Pending Invitations. There you will be able to see those who are Members Needing Approval (if they are coming into your system via a Registration Page that you designed), or Invited/Approved (if they simply have not yet clicked on the link in the Welcome email sent to them when they were entered into the People module, nor downloaded the BoosterHub app).